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91.
Introduction The MS=8.1 earthquake occurred in west of the Kunlun Pass on November 14, 2001. It is the greatest earthquake occurred in China since the last half of the century and is an important event in recent seismic history of China. Some specialists consider that the earthquake occurred in the area where the earthquake monitoring capability is lowest in Chinese mainland; no striking precursory seismicity was found. The study on the precursory seismicity before the earthquake has not b…  相似文献   
92.
湖北黄土岭麻粒岩锆石拉曼光谱和等离子体质谱研究   总被引:3,自引:0,他引:3  
对湖北黄土岭麻粒岩中锆石同时进行了激光拉曼探针、阴极发光 (CL)观察和U ,Th及Pb Pb年龄ICPMS测定 ,发现麻粒岩中部分锆石发生的不是固态重结晶作用 ,而是部分熔蚀 /沉淀再结晶过程。结合CL图像结构特征和2 0 7Pb/ 2 0 6Pb年龄初步推断 ,麻粒岩相事件发生在 2 0亿年之后。结构、化学和同位素组成的测定表明 ,大别地区广泛存在的燕山期热事件使锆石发生不同程度的变质重结晶作用 ,使锆石晶格愈合。  相似文献   
93.
电感耦合等离子体质谱(ICP-MS)技术在地学研究中的应用   总被引:30,自引:0,他引:30  
李冰  杨红霞 《地学前缘》2003,10(2):367-378
简单介绍ICP MS技术应用最新进展。着重对该技术在中国地学研究和多目标地质调查中的应用作一回顾 ,包括ICP MS技术简介和地质样品分析需求 ,稀土稀散等痕量、超痕量多元素分析 ,铂族元素分析 ,卤素等非金属元素分析 ,同位素比值分析等内容。着重对最近几年国内地质样品分析的一些新方法加以介绍。  相似文献   
94.
碱熔沉淀-等离子体质谱法测定地质样品中的多元素   总被引:14,自引:17,他引:14       下载免费PDF全文
采用过氧化钠焙融或偏硼酸锂熔融分解样品,将提取液碱性沉淀,通过过滤分离掉大量熔剂,再将沉淀用酸复溶后用等离子体质谱测定26个元素。通过对比,偏硼酸锂熔融—酸提取—碱性沉淀的方案,空白低,易操作,成本低,大多数元素测定结果的相对误差<10%,相对标准偏差<5%(n=10),与标准值相吻合。  相似文献   
95.
建立了HF—HN03密封酸溶以及Na2O2熔融处理样品,乙醇增强灵敏度,电感耦合等离子体质谱直接测定地质样品中微量和超痕量碲的方法。样品溶液中加入乙醇(φ=4%),在0.85L/min的载气流速下,碲信号可增强2.5倍以上。碲的方法检出限(100,DF=1000)为0.02μg/g。用土壤和水系沉积物国家一级标准物质验证了方法的准确度,标准物质的绝大多数分析结果与标准值的误差在允许范围内。分析了大洋多金属结核样品及深海沉积物样品中的微量碲,结果与其他方法相符,精密度试验RSD(n=3)<10%。  相似文献   
96.
超临界萃取/气相色谱—质谱测定油页岩中的生物标志物   总被引:4,自引:1,他引:3  
王海霞  饶竹 《岩矿测试》2000,19(2):86-92
采用超临界萃取 /气相色谱 -质谱技术测定了广东茂名油页岩中环己烷的链取代烃、甾烷、甾烯和藿烷等生物标志物 ,其分析结果与经典索式抽提和文献结果基本相符。该方法与索式抽提法相比简单、快速、无污染和危险 ,可用于油页岩等固体样品中生物标志物的分析  相似文献   
97.
海底X射线荧光探测系统的软件研制   总被引:2,自引:2,他引:0  
基于Windows98操作平台,结合软件工程的设计原则和面向对象的程序设计方法,用Visual Basic 6.0开发了海底X射线荧光探测系统软件(EDXRF^MS)。该软件能完成数据处理及运算,主要解决谱数据的采集与测量控制、成图和图形处理、X射线荧光谱分析、干扰因素的校正、仪器标定与含量计算等问题。EDXRF^MS软件与海底X射线荧光探测系统的硬件配合,能够进行海上现场多道数据的实时采集,对于海底矿产资源的开发具有一定的实用价值。  相似文献   
98.
地震地表破裂带调查表明,昆仑山口西 8. 1级地震的破裂长度为 426km,最大水平位移6m左右,地震破裂位移的分布明显地受断层活动段控制。该次地震的破裂长度远大于统计值,文中应用地壳极限线应变的概念,通过比较中国大陆内部几次走滑型强震的地震破裂最大位移与破裂长度的关系,论述了昆仑山口西 8. 1级地震中各次级段破裂的相对独立特征,认为该次强震不是一次整体性破裂事件,而是由连续触发的几次地震组成  相似文献   
99.
Irgarol 1051, a boosting antifouling agent often used to supplement copper based paints was found in surface waters from South Florida at stations collected from the Miami River, Biscayne Bay and selected areas of the Florida Keys. Concentrations of the herbicide ranged from below the method detection limit (1 ng/L) to as high as 182 ng/L in a canal system in Key Largo. The herbicide was present at 93% of the stations and often found in conjunction with its descyclopropyl metabolite (M1) previously reported to be the major degradation product of Irgarol under natural environmental conditions. The 90th percentile concentration calculated for all South Florida samples was 57.6 ng/L. Based on available data on the toxicity of Irgarol to algae and coral, only two stations (approximately 3%) ranked above the LC50 of 136 ng/L reported for the marine algae Naviculla pelliculosa and above the 100 ng/L level reported to reversibly inhibit photosynthesis of intact corals. However, a basic dissipation model for Irgarol using the Key Largo Harbor station as a point source indicated that concentrations of the herbicide decreased rapidly and concentrations below the MDL are observed within 2000 m of the source. No major coral based benthic habitats are documented for all the stations surveyed at distances that Irgarol may pose a substantial risk. However, other types of submerged vegetation like seagrasses are common around the marinas and the effects of Irgarol to such endpoints should be investigated further.  相似文献   
100.
Analytical perspective on trace element species of interest in exploration   总被引:1,自引:0,他引:1  
Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH2OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH2OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.  相似文献   
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